1) I have seen many boards with components placed by 45Deg. If you are using reflow soldering, I think that should be fine. If you are using wave soldering - then I do not know (I do not use wave soldering). But this is just my opinion. Just to be sure, you may want to double check it with your Assembly house.
2) If I have to use something like this, I would maybe place also some bigger caps (e.g. 10uF) between power and GND close to the block of components/connectors which are going to need power from that power rail (especially far end of this track). I would also use some smaller caps (e.g. 100nF) close to the power pins. The caps may help to filter the power and keep voltage level same even if there are some peaks in currents (+ that may help also whit EMC/EMI).
Basically, very simple to say, when you place a bigger cap at the far end of the power track (far away from power supply), this capacitor will be working as a small local power supply. So if there is a quick pulse which requires bigger current, the circuit doesn't have to take the power from the power supply, it will take it from the local capacitor which is much closer. Capacitor will then slowly be charged back from the power supply. That is much better situation, than travelling this bigger pulse through hole long power track. However, that is a very simple explanation